What is the lifespan of a lithium battery?
There are generally two ways to measure the lifespan of lithium batteries. One type is cycle life, which refers to the number of charge and discharge cycles a lithium battery can undergo before its capacity drops to a certain specified value (generally 80% of the initial capacity) under certain charge and discharge conditions. Another type is calendar life, which is calculated from the moment the battery is produced. Under certain environmental conditions, even if the battery is not in use, its performance will gradually decline over time until it can no longer meet the usage requirements.
2. Internal factors affecting the lifespan of lithium batteries
2.1 Electrode Materials
Different electrode materials have a significant impact on the lifespan of lithium batteries. For instance, lithium cobalt oxide electrode materials have a relatively high energy density, but their stability is relatively poor. They are prone to structural changes during charging and discharging, which leads to a rapid decline in battery capacity. The structure of lithium iron phosphate material is more stable, capable of withstanding more charge and discharge cycles, and its cycle life is relatively longer.
2.2 Electrolyte
The electrolyte plays a crucial role in the transmission of ions in lithium batteries. High-quality electrolyte should have good chemical stability, high ionic conductivity, and appropriate boiling point, flash point, etc. If the electrolyte undergoes decomposition, oxidation and other reactions during long-term use, a passivation film will form on the electrode surface, affecting the ion transport efficiency and thereby reducing the battery's performance and lifespan. Moreover, the purity of the electrolyte and the content of impurities can also affect the battery life. Impurities may trigger some side reactions and accelerate the aging of the battery.
2.3 Diaphragm
The separator is located between the positive and negative electrodes. Its main function is to prevent direct contact between the positive and negative electrodes and short circuits, while allowing lithium ions to pass through. High-quality diaphragms have good mechanical strength and chemical stability. If the separator is damaged during use or has adverse reactions with the electrolyte or electrodes,it will cause an internal short circuit in the battery or impede ion transmission, seriously affecting the battery's lifespan.
3. External factors affecting the lifespan of lithium batteries
3.1 Charge and Discharge rate
The charge and discharge rate refers to the current value required for a battery to discharge its rated capacity within a specified time. High-rate charging and discharging will generate a large amount of heat inside the battery, causing irreversible changes in the structure of the electrode materials. At the same time, it will also accelerate the decomposition of the electrolyte and the occurrence of of side reactions. For instance, during the fast charging process of electric vehicles, if high-power fast charging is frequently used, the lifespan of solar lithium batteries will be significantly shortened. On the contrary, charging and discharging at a lower rate can reduce these adverse effects and extend the battery life.
3.2 Temperature
Temperature has a significant impact on the lifespan of lithium batteries. In high-temperature environments, the chemical reaction rate of energy storage battery increases, and the stability of electrode materials and electrolytes decreases, which will accelerate the aging process of the battery. Long-term use or charging in a high-temperature environment may lead to problems such as battery swelling and a sharp decline in capacity. Although low-temperature environments do not cause as severe damage to battery structures as high-temperature ones, they can reduce the charging and discharging efficiency and available capacity of batteries. For instance, in the cold winter, the battery life of mobile phones declines, and the driving range of electric vehicles will also be greatly reduced. Moreover, frequent charging and discharging in low temperatures will also cause certain damage to the battery life.
3.3 Overcharging and overdischarging
Overcharging refers to the situation where the voltage of a battery exceeds its specified upper limit during charging, while overdischarging occurs when the voltage is lower than the specified lower limit during discharging. Overcharging can lead to structural damage of the positive electrode material, decomposition of the electrolyte to produce gas, increase the internal pressure of the battery, and even cause safety accidents. At the same time, it will also seriously shorten the battery life. Over-discharge will cause lithium metal to precipitate from the negative electrode material, resulting in irreversible capacity loss. Modern lithium batteries are generally equipped with a battery management system (BMS) to prevent overcharging and overdischarging. However, if the BMS malfunctions or substandard chargers and other devices are used, overcharging and overdischarging may still occur.
4. How to extend the lifespan of lithium batteries?
4.1 Charge and discharge reasonably
Try to avoid overcharging and overdischarging. When the device indicates low battery level, it should be charged in time. When charging, it is advisable to use the original charger as much as possible and avoid charging in high or low temperature environments. For electric vehicles, if it is not an emergency, it is advisable to choose slow charging as much as possible.
4.2 Control the ambient temperature for use
Avoid exposing lithium batteries to high-temperature environments for long periods of time, such as not placing mobile phones in cars directly exposed to sunlight. In a low-temperature environment, if possible, try to keep the device warm before using and charging it. For some lithium battery application scenarios that are sensitive to temperature, corresponding temperature control devices can also be equipped.
4.3 Regular maintenance and inspection
For some large-scale lithium battery energy storage systems or battery packs of electric vehicles, regular maintenance and inspection are very necessary. Professional detection equipment can be used to check the health status of batteries, changes in internal resistance, etc., to promptly identify potential problems and take corresponding measures, such as equalizing the battery.
In conclusion, the lifespan of lithium batteries is comprehensively influenced by a variety of internal and external factors. After understanding these factors, we can take corresponding measures during the use of lithium batteries to extend their lifespan, improve the economy and safety of lithium battery usage, and enable lifepo4 batteries to better serve our lives and production.